| Compound | Plant part | Pathway | Superclass | Class | Amount | Reference |
| 4-HYDROXY-CINNAMIC-ACID | flower | Shikimates and Phenylpropanoids | Phenylpropanoids (C6-C3) | Cinnamic acids and derivatives | - | Pagani, F. (1976). Phytoconstituents of Orchidaceae. part 1. components of Orchis sambucina and Orchis morio. Boll Chim Farm, 115, 407 |
| CAFFEIC-ACID | flower | Shikimates and Phenylpropanoids | Phenylpropanoids (C6-C3) | Cinnamic acids and derivatives | - | Pagani, F. (1976). Phytoconstituents of Orchidaceae. part 1. components of Orchis sambucina and Orchis morio. Boll Chim Farm, 115, 407 |
| CHRYSANTHEMIN | flower | Shikimates and Phenylpropanoids | Flavonoids | Anthocyanidins | - | Uphoff, W. (1979). Anthocyanins in the flowers of european orchids. Experientia, 35, 1013-1014 doi:10.1007/bf01949912 |
| CYANIDIN-3-O-BETA-(6''-O-OXALYL)-GLUCOSIDE | flower | Shikimates and Phenylpropanoids | Flavonoids | Anthocyanidins | - | Strack, D., Busch, E., Wray, V., Grotjahn, L., Klein, E. (1986). Cyanidin 3-oxalylglucoside in orchids. Z Naturforsch Ser C, 41(7/8), 707-711 doi:10.1515/znc-1986-7-808 |
| CYANIN | flower | Shikimates and Phenylpropanoids | Flavonoids | Anthocyanidins | - | Uphoff, W. (1979). Anthocyanins in the flowers of european orchids. Experientia, 35, 1013-1014 doi:10.1007/bf01949912 |
| EPIPACTIN | flower | - | - | - | - | Uphoff, W. (1979). Anthocyanins in the flowers of european orchids. Experientia, 35, 1013-1014 doi:10.1007/bf01949912 |
| HIRCINOL | tuber | Shikimates and Phenylpropanoids | Phenanthrenoids | Phenanthrenes | - | Fritzemeier, K.H., Kindl, H. (1983). 9,10-dihydrophenanthrenes as phytoalexins of Orchidaceae. Eur J Biochem, 133, 545-550 doi:10.1111/j.1432-1033.1983.tb07498.x |
| ISOQUERCETIN | flower | Shikimates and Phenylpropanoids | Flavonoids | Flavonols | - | Pagani, F. (1976). Phytoconstituents of Orchidaceae. part 1. components of Orchis sambucina and Orchis morio. Boll Chim Farm, 115, 407 |
| MECOCYANIN | flower | Shikimates and Phenylpropanoids | Flavonoids | Anthocyanidins | - | Uphoff, W. (1979). Anthocyanins in the flowers of european orchids. Experientia, 35, 1013-1014 doi:10.1007/bf01949912 |
| ORCHICYANIN I | flower | - | - | - | - | Uphoff, W. (1979). Anthocyanins in the flowers of european orchids. Experientia, 35, 1013-1014 doi:10.1007/bf01949912 |
| ORCHICYANIN II | flower | - | - | - | - | Uphoff, W. (1979). Anthocyanins in the flowers of european orchids. Experientia, 35, 1013-1014 doi:10.1007/bf01949912 |
| ORCHINOL | tuber | Shikimates and Phenylpropanoids | Phenanthrenoids | Phenanthrenes | - | Fritzemeier, K.H., Kindl, H. (1983). 9,10-dihydrophenanthrenes as phytoalexins of Orchidaceae. Eur J Biochem, 133, 545-550 doi:10.1111/j.1432-1033.1983.tb07498.x |
| QUERCIMERITRIN | flower | Shikimates and Phenylpropanoids | Flavonoids | Flavonols | - | Pagani, F. (1976). Phytoconstituents of Orchidaceae. part 1. components of Orchis sambucina and Orchis morio. Boll Chim Farm, 115, 407 |