| Compound | Plant part | Pathway | Superclass | Class | Amount | Reference |
| (-)-LOLIOLIDE | - | Terpenoids | Apocarotenoids | Apocarotenoids (β-) | - | Pettit, G.R., Herald, C.L., Ode, R.H., Brown, P., Gust, D.J., Michel, C. (1980). Antineoplastic agents.69. the isolation of loliolide from an indian ocean opisthobranch mollusc. J Nat Prod, 43(6), 752-755 doi:10.1021/np50012a009 |
| (-)-LOLIOLIDE | leaf | Terpenoids | Apocarotenoids | Apocarotenoids (β-) | - | Hodges, P.O.R.T.E. (1964). Structure of loliolide. terpene from Lolium perenne. Tetrahedron, 20(6), 1463-1467 |
| BETA-CARBOLINE | - | Alkaloids | Tryptophan alkaloids | Carboline alkaloids | - | Bush, L.P., Jeffreys, J.A.D. (1975). Isolation and separation of tall fescue and ryegrass alkaloids. J Chromatogr, 111, 165 doi:10.1016/s0021-9673(01)80158-8 |
| BETA-CARBOLINE | aerial parts | Alkaloids | Tryptophan alkaloids | Carboline alkaloids | - | Zakaria, M.B., Jeffreys, J.A.D. (1986). The isolation of beta-carboline from Lolium perenne L. Malaysian J Sci, 8, 115-119 |
| BETA-CAROTENE | - | Terpenoids | Carotenoids (C40) | Carotenoids (C40, β-β) | - | Tamas, V., Popescu, V. (1985). Carotenoid pigments in some varieties and populations of Lolium perenne. Stud Ceret Biochim, 28(2), 152-154 |
| CHOLESTEROL | - | Terpenoids | Steroids | Cholestane steroids | - | Hamilton, R.J., Power, D.M. (1969). The chemical composition of the surface wax of Lolium perenne. Phytochemistry, 8(9), 1771-1775 doi:10.1016/s0031-9422(00)85967-1 |
| FESTUCINE | - | Alkaloids | Ornithine alkaloids | Pyrrolizidine alkaloids | - | Bush, L.P., Jeffreys, J.A.D. (1975). Isolation and separation of tall fescue and ryegrass alkaloids. J Chromatogr, 111, 165 doi:10.1016/s0021-9673(01)80158-8 |
| FLAVOXANTHIN | - | Terpenoids | Carotenoids (C40) | Carotenoids (C40, β-ε) | - | Tamas, V., Popescu, V. (1985). Carotenoid pigments in some varieties and populations of Lolium perenne. Stud Ceret Biochim, 28(2), 152-154 |
| HALOSTACHYINE | - | Alkaloids | Tyrosine alkaloids | Phenylethylamines | - | Bush, L.P., Jeffreys, J.A.D. (1975). Isolation and separation of tall fescue and ryegrass alkaloids. J Chromatogr, 111, 165 doi:10.1016/s0021-9673(01)80158-8 |
| HARMAN | - | Alkaloids | Tryptophan alkaloids | Carboline alkaloids | - | Bush, L.P., Jeffreys, J.A.D. (1975). Isolation and separation of tall fescue and ryegrass alkaloids. J Chromatogr, 111, 165 doi:10.1016/s0021-9673(01)80158-8 |
| HISTAMINE | - | Alkaloids | Histidine alkaloids | Imidazole alkaloids | - | Fowler, H.D. (1962). Histamine in grasses and clovers. Nature(London), 193, 582-583 doi:10.1038/193582a0 |
| LOLICINE A | seed | Alkaloids | Tryptophan alkaloids | Indole-Diterpenoid alkaloids (Penitrems) | - | Munday-finch, S.C., Wilkins, A.L., Miles, C.O. (1998). Isolation of lolicine a, lolicine b, lolitriol, and lolitrem n from Lolium perenne infected with Neotyphodium lolii and evidence for the natural occurrence of 31-epilolitrem n and 31-epilolitrem F. J Agr Food Chem, 46(2), 590-598 doi:10.1021/jf9706787 |
| LOLICINE B | seed | Alkaloids | Tryptophan alkaloids | Indole-Diterpenoid alkaloids (Penitrems) | - | Munday-finch, S.C., Wilkins, A.L., Miles, C.O. (1998). Isolation of lolicine a, lolicine b, lolitriol, and lolitrem n from Lolium perenne infected with Neotyphodium lolii and evidence for the natural occurrence of 31-epilolitrem n and 31-epilolitrem F. J Agr Food Chem, 46(2), 590-598 doi:10.1021/jf9706787 |
| LOLITREM B | - | Alkaloids | Tryptophan alkaloids | Indole-Diterpenoid alkaloids (Penitrems) | - | Gallagher, R.T., Hawkes, A.D., Steyn, P.S., Vleggaar, R. (1984). Tremorgenic neurotoxins from perennial ryegrass causing ryegrass staggers disorder of livestock: structure elucidation of Lolitrem B. Chem Commun, (9), 614-616 doi:10.1039/c39840000614 |
| LOLITREM B | fruit | Alkaloids | Tryptophan alkaloids | Indole-Diterpenoid alkaloids (Penitrems) | - | Weedon, C.M., Mantle, P.G. (1987). Paxilline biosynthesis by acremonium loliae. a step towards defining the origin of lolitrem neurotoxins. Phytochemistry, 26(4), 969-971 doi:10.1016/s0031-9422(00)82327-4 |
| LOLITREM B | seed | Alkaloids | Tryptophan alkaloids | Indole-Diterpenoid alkaloids (Penitrems) | - | Miles, C.O., Munday, S.C., Wilkins, A.L., Ede, R.M., Towers, N.R. (1994). Large-scale isolation of lolitrem b and structure determination of lolitrem E. J Agr Food Chem, 42(7), 1488-1492 doi:10.1021/jf00043a018 |
| LOLITREM E | seed | - | - | - | - | Miles, C.O., Munday, S.C., Wilkins, A.L., Ede, R.M., Towers, N.R. (1994). Large-scale isolation of lolitrem b and structure determination of lolitrem E. J Agr Food Chem, 42(7), 1488-1492 doi:10.1021/jf00043a018 |
| LOLITREM N | seed | - | - | - | - | Munday-finch, S.C., Wilkins, A.L., Miles, C.O. (1998). Isolation of lolicine a, lolicine b, lolitriol, and lolitrem n from Lolium perenne infected with Neotyphodium lolii and evidence for the natural occurrence of 31-epilolitrem n and 31-epilolitrem F. J Agr Food Chem, 46(2), 590-598 doi:10.1021/jf9706787 |
| LOLITRIOL | seed | Alkaloids | Tryptophan alkaloids | Indole-Diterpenoid alkaloids (Penitrems) | - | Munday-finch, S.C., Wilkins, A.L., Miles, C.O. (1998). Isolation of lolicine a, lolicine b, lolitriol, and lolitrem n from Lolium perenne infected with Neotyphodium lolii and evidence for the natural occurrence of 31-epilolitrem n and 31-epilolitrem F. J Agr Food Chem, 46(2), 590-598 doi:10.1021/jf9706787 |
| LUTEIN | - | Terpenoids | Carotenoids (C40) | Carotenoids (C40, β-ε) | - | Tamas, V., Popescu, V. (1985). Carotenoid pigments in some varieties and populations of Lolium perenne. Stud Ceret Biochim, 28(2), 152-154 |
| PAXILLINE | fruit | Alkaloids | - | - | - | Weedon, C.M., Mantle, P.G. (1987). Paxilline biosynthesis by acremonium loliae. a step towards defining the origin of lolitrem neurotoxins. Phytochemistry, 26(4), 969-971 doi:10.1016/s0031-9422(00)82327-4 |
| PERAMINE | - | Alkaloids | - | - | - | Rowan, D.D., Hunt, M.B., Gaynor, D.L. (1986). Peramine, a novel insect feeding deterrent from ryegrass infected with the endophyte Acremonium ioliae. Chem Commun, (12), 935-936 doi:10.1039/c39860000935 |
| PERLOLIDINE | - | Alkaloids | Anthranilic acid alkaloids | Quinazoline alkaloids | - | Bush, L.P., Jeffreys, J.A.D. (1975). Isolation and separation of tall fescue and ryegrass alkaloids. J Chromatogr, 111, 165 doi:10.1016/s0021-9673(01)80158-8 |
| PERLOLIDINE | aerial parts | Alkaloids | Anthranilic acid alkaloids | Quinazoline alkaloids | - | Zakaria, M.B., Jeffreys, J.A.D. (1986). The isolation of beta-carboline from Lolium perenne L. Malaysian J Sci, 8, 115-119 |
| PERLOLINE | - | Alkaloids | Tyrosine alkaloids | Isoquinoline alkaloids | - | Bush, L.P., Jeffreys, J.A.D. (1975). Isolation and separation of tall fescue and ryegrass alkaloids. J Chromatogr, 111, 165 doi:10.1016/s0021-9673(01)80158-8 |
| PERLOLINE | aerial parts | Alkaloids | Tyrosine alkaloids | Isoquinoline alkaloids | - | Sachse, J. (1980). Determination of perloline in grass species. J Chromatogr, 192, 199-207 |
| PERLOLINE | aerial parts | Alkaloids | Tyrosine alkaloids | Isoquinoline alkaloids | - | Zakaria, M.B., Jeffreys, J.A.D. (1986). The isolation of beta-carboline from Lolium perenne L. Malaysian J Sci, 8, 115-119 |
| PERLOLYRINE | - | Alkaloids | Tryptophan alkaloids | Carboline alkaloids | - | Bush, L.P., Jeffreys, J.A.D. (1975). Isolation and separation of tall fescue and ryegrass alkaloids. J Chromatogr, 111, 165 doi:10.1016/s0021-9673(01)80158-8 |
| PEROLINE | aerial parts | - | - | - | - | Yates, S.G., Rogovin, S.P., Bush, L.P., Buckner, R.C., Boling, J.A. (1975). Isolation of perloline, the yellow alkaloid of tall fescue. Ind Eng Chem Prod Res Dev, 14, 315 doi:10.1021/i360056a607 |
| RESVERATROL | seed | Shikimates and Phenylpropanoids | Stilbenoids | Monomeric stilbenes | - | Powell, R.G., Tepaske, M.R., Plattner, R.D., White, J.F., Clement, S.L. (1994). Isolation of resveratrol from Festuca versuta and evidence for the widespread occurrence of this stilbene in the Poaceae. Phytochemistry, 35(2), 335-338 doi:10.1016/s0031-9422(00)94759-9 |
| TRANS-VIOLAXANTHIN | - | Terpenoids | Carotenoids (C40) | Carotenoids (C40, β-β) | - | Tamas, V., Popescu, V. (1985). Carotenoid pigments in some varieties and populations of Lolium perenne. Stud Ceret Biochim, 28(2), 152-154 |