LOLICINE B
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Name
LOLICINE B
IUPAC name
(2S,4R,4aS,4bR,6aS,8aR,11aR,15bS,15cS,17aS)-4-hydroxy-2-(2-hydroxypropan-2-yl)-4a-methoxy-9,9,11,11,15b,15c-hexamethyl-3,4,4a,5,6,6a,7,8,8a,9,11,11a,15,15b,15c,16,17,17a-octadecahydro-2H-chromeno[5',6':6,7]indeno[1,2-b]isobenzofuro[5,6-e]indol-12(4bH)-one
SMILES
C[C@]12CC[C@H]8[C@]([C@@H]1CC[C@@H]3[C@@]2(C4=C(C3)C5=C([N]4)C=CC6=C5C[C@@H]7[C@@H](C6=O)C(OC7(C)C)(C)C)C)([C@@H](C[C@H](O8)C(C)(C)O)O)OC
Molecular formula
C38H52NO6
Molecular weight
618.84 g/mol
Monoisotopic mass
618.3795 Da
Pathway:
Superclass:
Class:
Glycoside:
No
Chemical classification: NPClassifier (Kim et al., 2021)
| Plant | Plant part | Amount | Reference |
|---|---|---|---|
| Lolium perenne L. | seed | - |
Munday-finch, S.C., Wilkins, A.L., Miles, C.O. (1998). Isolation of lolicine a, lolicine b, lolitriol, and lolitrem n from Lolium perenne infected with Neotyphodium lolii and evidence for the natural occurrence of 31-epilolitrem n and 31-epilolitrem F. J Agr Food Chem, 46(2), 590-598 doi:10.1021/jf9706787
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