DIOSGENIN-3-O-(ALPHA-L-RHAMNOPYRANOSYL(1-2))-BETA-D-GLUCOPYRANOSIDE
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Name
DIOSGENIN-3-O-(ALPHA-L-RHAMNOPYRANOSYL(1-2))-BETA-D-GLUCOPYRANOSIDE
IUPAC name
(2R,3S,4S,5S,6R)-2-(((2S,3S,4R,5R,6S)-4,5-dihydroxy-6-(hydroxymethyl)-2-(((4S,5'R,6aR,6bS,8aS,8bR,9S,10R,11aS,12aS,12bS)-5',6a,8a,9-tetramethyl-1,3,3',4,4',5,5',6,6a,6b,6',7,8,8a,8b,9,11a,12,12a,12b-icosahydrospiro[naphtho[2',1':4,5]indeno[2,1-b]furan-10,2'-pyran]-4-yl)oxy)tetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triol
SMILES
C[C@@H]8CC[C@@]1([C@H]([C@H]2[C@@H](O1)C[C@@H]3[C@@]2(CC[C@H]4[C@H]3CC=C5[C@@]4(CC[C@@H](C5)O[C@@H]6[C@H]([C@@H]([C@H]([C@H](CO)O6)O)O)O[C@@H]7[C@H]([C@H]([C@@H]([C@@H](C)O7)O)O)O)C)C)C)OC8
Molecular formula
C39H62O12
Molecular weight
722.91 g/mol
Monoisotopic mass
722.4241 Da
Chemical classification: NPClassifier (Kim et al., 2021)
| Plant | Plant part | Amount | Reference |
|---|---|---|---|
| Allium vineale L. | bulb | - |
Chen, S.X., Snyder, J.K. (1987). Wolluscidal saponins from Allium vineale. Tetrahedron Lett, 28(46), 5603-5606 doi:10.1016/s0040-4039(00)96791-1
|
| Allium vineale L. | bulb | - |
Chen, S.X., Snyder, J.K. (1989). Diosgenin-bearing, molluscicidal saponins from Allium vineale: an nmr approach for the structural assignment of oligosaccharide units. J Org Chem, 54(15), 3679-3689 doi:10.1021/jo00276a033
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